
Vinyl Acetate Emulsion Polymerization and Copolymerization With Acrylic Monomers
by Erbil; Yildirim H.-
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Summary
Author Biography
Table of Contents
INTRODUCTION | |
EMULSION POLYMERIZATION | |
Emulsion Polymerization of Hydrophobic Monomers | |
Inverse and Emulsifier Free Emulsion Polymerizations | |
Vinyl Acetate Emulsion Polymerization | |
Radiation Induced Vinyl Acetate Emulsion Polymerization | |
THE ROLE OF INGREDIENTS IN VINYL ACETATE EMULSION | |
Monomer Quality and Inhibitors | |
Initiators | |
Emulsifiers | |
Protective Colloids | |
PH and Ionic Strength Controllers | |
Others | |
THEORY AND KINETICS OF VINYL ACETATE HOMOPOLYMERIZATION | |
Effect of Monomer Concentration | |
Effect of Initiator Concentration and Type | |
Effect of Emulsifier Concentration and Type | |
Particle Nucleation Mechanisms | |
Thermodynamics and Kinetics of Particle Morphology Control | |
VINYL ACETATE COPOLYMERIZATION WITH ACRYLIC MONOMERS | |
Reactivity Ratios | |
Propagation Rate in Copolymerization | |
Controlled Monomer Addition | |
The Effect of the Type of the Acrylic Monomer | |
The Effect of the Vinyl Acetate/Acrylic Monomer Feed Ratio | |
COLLOIDAL STABILITY OF VINYL ACETATE HOMO AND COPOLYMERS | |
Basic Phenomena | |
Steric Stabilization | |
Coagulation | |
Ionic Effects | |
EXPERIMENTAL DETERMINATION OF LATTICE PROPERTIES | |
Viscosity | |
Solids Content | |
Free Monomer Content | |
Mean Molecular Weight and Molecular Weight Distribution | |
Graft and Cross-Linked Polymer Content | |
Monomer Sequence Distribution | |
Mean Particle Size and Particle Size Distribution | |
Chemical Composition of Copolymers | |
Scattering of Colloids Surfactant Adsorption on Latex/Water Interface | |
Colloidal Stability | |
Drying and Film Forming Properties of Latices | |
Surface Tension of Dried Latex Films | |
Dynamic Mechanical Properties of Latex Films | |
Aging Properties | |
FACTORS AFFECTING THE FINAL P ROPERTIES OF THE POLYVINYL ACETATE-BASED LATICES | |
The Role of the Type and the Quality of the {Polyvinyl Alcohol Protective Colloids on PVAc Homopolymers | |
The Role of Emulsifiers on the Mean Particle Size and Colloidal Stability | |
The Stabilization of PVAc Latices by Monomeric Carboxylic Groups | |
The Role of the Duration of Polymerization Reaction | |
The Role of Acrylic Comonomers | |
The Role of Monomer Addition Methods and Propagation Rates on Copolymer Composition in Semi-Batch Reactor Operations | |
The Role of the Shapes of Reactor Stirrers and Baffles and Stirring Rate | |
The Role of Antifoaming Agents | |
Seed Latex Preparation and Use | |
Emulsion Polymerization in Continuous Reactors | |
Scale-Up Problems | |
OVERVIEW OF THE USES OF POLYVINYL ACETATE-BASED LATICES | |
SOME NEW APPLICATIONS IN INDUSTRY | |
Ultrasound Sensor Monitoring of Emulsion Polymerization | |
Loop Reactor Continuous Emulsion Polymerization |
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