Macromolecules Containing Metal and Metal-Like Elements, Volume 9: Supramolecular and Self-Assembled Metal-Containing Materials,
by Editor: Alaa S. Abd-El-Aziz (Department of Chemistry, The University of Winnipeg, Winnipeg, Manitoba, Canada); Editor: Charles E. Carraher (Florida Atlantic Univ., Boca Raton); Editor: Charles U. Pittman (Department of Chemistry, Mississippi StateFormat: eBook
Pub. Date: 2009-11-01
Publisher(s): Wiley
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Summary
This book series Macromolecules Containing Metal and Metal-like Elements brings new concepts and developments in the titled area of research. Volume 9 focuses attention on the area of supramolecular chemistry, supramolecular architecture and supramolecular self-assemblies that involve materials containing metals and metal-like elements and the potential applications of these interesting hybrid materials.
Table of Contents
| Preface | |
| Series Preface | |
| Supramolecular Structures and Functions with Inorganic Building Blocks | |
| Introduction | |
| Hybrid Lipid Thin Films | |
| Layer-by-Layer Assemblies | |
| Structure Transcription | |
| Functional Mesoporous Hybrids | |
| Future Perspectives | |
| Acknowledgments | |
| References | |
| Self-Assembly of Hydrophilic Polyoxometalate Macroanions in Dilute Solutions | |
| Introduction | |
| Solution Behavior of POM Macroions: Soluble but Still Aggregate | |
| Characterization of the Supramolecular Structures | |
| Controlling the Blackberry Formation and Blackberry Size by Changing Solvent Quality | |
| Counterion Association around Discrete POM Macroions | |
| Counterion Condensation around Blackberries | |
| Identification of the Driving Forces Responsible for the Blackberry Formation | |
| Soft Nature of the Blackberries-Effect of Additional Hydrogen Bonding | |
| Weak Electrolyte Type POMs | |
| Effect of Additional Electrolytes | |
| Kinetic Process of Blackberry Formation | |
| Cation Transport over the Anionic Blackberry Membrane | |
| Macroions in Solution: An important Linkage among Simple Ions, Polymers, Colloids, and Biosystems | |
| Conclusions | |
| Acknowledgments | |
| References | |
| Supramolecular Structures and Polyoxometalates | |
| Introduction | |
| Supramolecular Features of Polyoxometalate-Supported Transition-Metal Complexes | |
| Polyoxometalate Crown Ether Complexes with Supramolecular cations | |
| Supramolecular Water Clusters Associated with Polyoxometalates | |
| Concluding Remarks | |
| Acknowledgements | |
| References | |
| Supramolecular Coordination Networks Employing Sulfonate and Phosphonate Linkers: From Layers to Open Structures | |
| Introduction | |
| The Sulfonate Group as a Ligand | |
| Layered Metal Sulfonates | |
| Nonlayered Metal Sulfonates | |
| Dynamic and Crystalline Metal Sulfonate Frameworks | |
| Hydrogen Bonded Second Sphere Coordination Networks | |
| Metal phosphonates | |
| Conclusion | |
| References | |
| Transition-Metal-Based Linear Chain Compounds | |
| Introduction | |
| Ligand-Supported Metal Chains | |
| Linear Chains of Chromium | |
| Linear Metal Chains of Cobalt | |
| Linear Chains of Copper | |
| Linear Chains of Nickel | |
| Linear Chains of Palladium | |
| Unsupported Metal Chains | |
| Linear Chain Compounds of Rhodium | |
| Linear Chain of Iridium | |
| The Platinum Blues | |
| Concluding Remarks | |
| References | |
| Boronate-Linked Materials: Ranging from Amorphous Assemblies to Highly Structured Networks | |
| Introduction and Scope | |
| Supramolecular Boronate Assemblies | |
| Traditional Hydrogen Bonded Supramolecular Assemblies | |
| Novel Phenyl-Boron-Phenyl Sandwich Supramolecular Assembly | |
| Coordination-Based Macrocyclic Assemblies | |
| Coordination-Based Linear Assemblies | |
| Covalently Linked Boronate Assemblies | |
| Covalently Linked Macrocyclic and Cage Assemblies | |
| Covalently Linked Linear Assemblies | |
| Covalently Linked Network Assemblies | |
| Summary and Outlook | |
| References | |
| Mixed-Metal Supramolecular Complexes Coupling Polyazine Light Absorbers and Reactive Metal Centers | |
| Introduction | |
| Light Absorption | |
| Solar Water Splitting | |
| Metal Complexes as DNA Targeting Agents | |
| Supramolecular Charge Transfer Complexes | |
| Cyclic Voltammetry of Charge Transfer Light Absorbers | |
| Supramolecular Complexes Coupling Ru(II) or Os(II) Polyazine Light Absorbers and Rh(III) Reactive Metal Centers | |
| The Complexes [(bpy)2Ru(BL)RhH2(PPh3)2]3+ | |
| Cyanide-Bridged Ru(II)-Rh(III) Complexes | |
| Polyazine-Bridged [(bpy)2Ru(dpp)Rh(bPy)2 5+ | |
| Tridentate-Bridged Complexes: [(ttpy)Ru(tpy-(Ph)n-tpy) Rh(ttpy)]5+(n=0-2) | |
| Ru(II)-Rh(III) Complexes Bridged with a Flexible Spacer: [(Me2phen)2Ru(Mebpy-CH2-CH2-Mebpy)Rh(Me2bpy)2]5+ | |
| Dendrimeric Ru(II)/Os(II)-Rh(III) Complexes: [M{(dpp)Rh(ppy)2}3](PF6)5 | |
| Extended Supramolecular Architectures with Fe(II)/Ru(II)/Rh(III) | |
| Stereochemically Defined Tridentate-Bridged Ru(II)-Rh(III) Complex | |
| Photoinitiated Electron Collection | |
| Supramolecular Complexes Coupling Ru(II) or Os(II) Polyazine Light Absorbers to Reactive Pt(II) Metal Centers | |
| Cyanide-Bridged Ru(II)-Pt(II) Complexes: [(bpy)2(CN)Ru(CN)Pt(dien)](ClO4)2 and [(dien)Pt(NC)(bpy)2Ru(CN)Pt(dien)](ClO4)4 | |
| A Ru(II)-Pt(II) Complex as a Chemodosimeter | |
| Ru(II)-Pt(II) Complexes Bridged by Flexible Spacers | |
| A bpm-Bridged Ru(II)-Pt(II) Complex: [(bpy)2Ru(bpm)PtCl2]2+ | |
| Ru(II)-Pt(II) dpp-Bridged Complexes: [(bpy)2Ru(dpp) PtMe2]2+ and [(bpy)2Ru(dpp)PtCl2]2+ | |
| Ru(II)-Pt(II) Complexes Bridged by a BL Ligand with Two Inequivalent Sites | |
| DNA Binding of the Ru(II)-Pt(II) Complex: [(tpy)Ru(dtdeg)PtCl]Cl3 | |
| Ru(II)-Pt(II) Complexes with Amino Linkages: [(bpy)2Ru(BL)PtCl2](PF6)2 (BL = bpy(CONH (CH2)3NH2)2 and phenNHCO(COOHbpy)) | |
| Systematic Studies of Ru(II)/Os(II)-Pt(II) Complexes with Polyazine Bridging Ligands | |
| Dendrimeric Ru(II)-Pt(II) Complexes Bridged by Polyazine Bridging Ligands | |
| Supramolecular Complexes Coupling Ru(II) Polyazine Light Absorbers to Reactive Pd(II) Metal Centers | |
| Ru(II)-Pd(II) Complexes Bridged by dpp and bpm Ligands: [(bpy)2Ru(dpp)PdCl2](PF6)2 and [(bpy)2Ru(bpm)PdCl2](ClO4)2 | |
| Ru(II)-Pd(II) Complexes Bridged by an Extended Polyazine Ligand: [(tBu2bpy)2Ru(tpphz)PdCl2](PF6)2 | |
| Ru(II)-Pd(II) Complexes Bridged by bpm type Ligands: [(bpy)2Ru(BL)PdMeCl]2+ | |
| A Ru(II)-Pd(II) Complex Bridged by a Flexible Polyazine Bridging Ligand: [(bpy)2Ru(DMB)PdCl2]2+ | |
| Conclusions | |
| Acknowledgments | |
| References | |
| Supramolecular Hybrid Materials-Integrating Functionality with Sensing | |
| Introduction | |
| Enhanced Coordination by Preorganization. Surface Chelate Effect and Signaling | |
| Enhanced Signaling by Preorganization | |
| Assembly-Disassembly | |
| Selectivity by Polarity and Size. Biomimetic Signaling | |
| Switching, Gating and Signaling | |
| Conclusions | |
| Acknowledgments | |
| References | |
| Molecular Recognition Process between Nucleobases and Metal-Oxalato Frameworks | |
| Introduction | |
| Molecular Recognition | |
| Nucleobases | |
| Oxalate | |
| Metal-Oxalato-Nucleobase Extended Systems | |
| Other metal-nucleobase 1D Extended Systems | |
| Hybrid Systems Based on Metal-Oxalato and Protonated Nucleobases | |
| Conclusions | |
| References | |
| Crystal Engineering of Coordination Polymers | |
| Introduction | |
| Synthetic Approaches | |
| The Node-and-Spacer Paradigm | |
| Flexible Ligand Approach: Polycarboxylates as Anionic Linkers. A Case Study-Malonato Complexes | |
| The Building-Block Approach | |
| Conclusions and Perspectives | |
| Acknowledgments | |
| References | |
| Index | |
| Table of Contents provided by Publisher. All Rights Reserved. |
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