
Inorganic Chemistry
by House, James E.-
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Summary
Table of Contents
Preface to the Second Edition | p. xi |
Preface to the First Edition | p. xii |
Structure of Atoms and Molecules | p. 1 |
Light, Electrons, and Nuclei | p. 3 |
Some Early Experiments in Atomic Physics | p. 3 |
The Nature of Light | p. 7 |
The Bohr Model | p. 11 |
Particle-Wave Duality | p. 14 |
Electronic Properties of Atoms | p. 16 |
Nuclear Binding Energy | p. 21 |
Nuclear Stability | p. 23 |
Types of Nuclear Decay | p. 25 |
Predicting Decay Modes | p. 28 |
Basic Quantum Mechanics and Atomic Structure | p. 33 |
The Postulates | p. 33 |
The Hydrogen Atom | p. 40 |
The Helium Atom | p. 45 |
Slater Wave Functions | p. 47 |
Electron Configurations | p. 49 |
Spectroscopic States | p. 54 |
Covalent Bonding in Diatomic Molecules | p. 61 |
The Basic Ideas of Molecular Orbital Methods | p. 61 |
The H2+ and H2 Molecules | p. 69 |
Diatomic Molecules of Second-Row Elements | p. 71 |
Photoelectron Spectroscopy | p. 77 |
Heteronuclear Diatomic Molecules | p. 79 |
Electronegativity | p. 82 |
Spectroscopic States for Molecules | p. 85 |
A Survey of Inorganic Structures and Bonding | p. 89 |
Structures of Molecules Having Single Bonds | p. 89 |
Resonance and Formal Charge | p. 99 |
Complex Structures: A Preview of Coming Attractions | p. 111 |
Electron-Deficient Molecules | p. 119 |
Structures Having Unsaturated Rings | p. 121 |
Bond Energies | p. 123 |
Symmetry and Molecular Orbitals | p. 129 |
Symmetry Elements | p. 129 |
Orbital Symmetry | p. 137 |
A Brief Look at Group Theory | p. 139 |
Construction of Molecular Orbitals | p. 144 |
Orbitals and Angles | p. 150 |
Simple Calculations Using the Hückel Method | p. 152 |
Condensed Phases | p. 167 |
Dipole Moments and Intermolecular Interactions | p. 169 |
Dipole Moments | p. 169 |
Dipole-Dipole Forces | p. 174 |
Dipole-Induced Dipole Forces | p. 176 |
London (Dispersion) Forces | p. 177 |
The van der Waals Equation | p. 181 |
Hydrogen Bonding | p. 183 |
Cohesion Energy and Solubility Parameters | p. 192 |
Solvatochromism | p. 196 |
Ionic Bonding and Structures of Solids | p. 201 |
Energetics of Crystal Formation | p. 201 |
Madelung Constants | p. 205 |
The Kapustinskii Equation | p. 209 |
Ionic Sizes and Crystal Environments | p. 210 |
Crystal Structures | p. 213 |
Solubility of Ionic Compounds | p. 219 |
Proton and Electron Affinities | p. 224 |
Structures of Metals | p. 227 |
Defects in Crystals | p. 230 |
Phase Transitions in Solids | p. 233 |
Heat Capacity | p. 234 |
Hardness of Solids | p. 237 |
Dynamic Processes in Inorganic Solids | p. 243 |
Characteristics of Solid-State Reactions | p. 243 |
Kinetic Models for Reactions in Solids | p. 245 |
Thermal Methods of Analysis | p. 253 |
Effects of Pressure | p. 254 |
Reactions in Some Solid Inorganic Compounds | p. 256 |
Phase Transitions | p. 258 |
Reactions at Interfaces | p. 262 |
Diffusion in Solids | p. 263 |
Sintering | p. 265 |
Drift and Conductivity | p. 267 |
Acids, Bases, and Solvents | p. 271 |
Acid-Base Chemistry | p. 273 |
Arrhenius Theory | p. 273 |
Brønsted-Lowry Theory | p. 276 |
Factors Affecting the Strength of Acids and Bases | p. 279 |
Acid-Base Character of Oxides | p. 284 |
Proton Affinities | p. 286 |
Lewis Theory | p. 288 |
Catalytic Behavior of Acids and Bases | p. 292 |
The Hard-Soft Interaction Principle (HSIP) | p. 296 |
Electronic Polarizabilities | p. 305 |
The Drago Four-Parameter Equation | p. 306 |
Chemistry in Nonaqueous Solvents | p. 313 |
Some Common Nonaqueous Solvents | p. 313 |
The Solvent Concept | p. 314 |
Amphoteric Behavior | p. 316 |
The Coordination Model | p. 317 |
Chemistry in Liquid Ammonia | p. 318 |
Liquid Hydrogen Fluoride | p. 324 |
Liquid Sulfur Dioxide | p. 326 |
Superacids | p. 330 |
Chemistry of the Elements | p. 335 |
Chemistry of Metallic Elements | p. 337 |
The Metallic Elements | p. 337 |
Band Theory | p. 338 |
Groups IA and IIA Metals | p. 341 |
Zintl Phases | p. 349 |
Aluminum and Beryllium | p. 351 |
The First-Row Transition Metals | p. 353 |
Second- and Third-Row Transition Metals | p. 355 |
Alloys | p. 357 |
Chemistry of Transition Metals | p. 360 |
The Lanthanides | p. 367 |
Organometallic Compounds of the Main Group Elements | p. 375 |
Preparation of Organometallic Compounds | p. 376 |
Organometallic Compounds of Group IA Metals | p. 378 |
Organometallic Compounds of Group IIA Metals | p. 380 |
Organometallic Compounds of Group IIIA Metals | p. 383 |
Organometallic Compounds of Group IVA Metals | p. 387 |
Organometallic Compounds of Group VA Elements | p. 388 |
Organometallic Compounds of Zn, Cd, and Hg | p. 389 |
Chemistry of Nonmetallic Elements I. Hydrogen, Boron, Oxygen, and Carbon | p. 393 |
Hydrogen | p. 393 |
Boron | p. 400 |
Oxygen | p. 411 |
Carbon | p. 420 |
Chemistry of Nonmetallic Elements II Groups IVA and VA | p. 439 |
The Group IVA Elements | p. 439 |
Nitrogen | p. 456 |
Phosphorus, Arsenic, Antimony, and Bismuth | p. 471 |
Chemistry of Nonmetallic Elements EL Groups VIA-VTIIA | p. 499 |
Sulfur, Selenium, and Tellurium | p. 499 |
The Halogens | p. 520 |
The Noble Gases | p. 538 |
Chemistry of Coordination Compounds | p. 551 |
Introduction to Coordination Chemistry | p. 553 |
Structures of Coordination Compounds | p. 553 |
Metal-Ligand Bonds | p. 557 |
Naming Coordination Compounds | p. 559 |
Isomerism | p. 561 |
A Simple Valence Bond Description of Coordinate Bonds | p. 568 |
Magnetism | p. 572 |
A Survey of Complexes of First-Row Metals | p. 574 |
Complexes of Second- and Third-Row Metals | p. 576 |
The 18-Electron Rule | p. 576 |
Back Donation | p. 580 |
Complexes of Dinitrogen, Dioxygen, and Dihydrogen | p. 585 |
Ligand Fields and Molecular Orbitals | p. 591 |
Splitting of d Orbital Energies in Octahedral Fields | p. 591 |
Splitting of d Orbital Energies in Fields of Other Symmetry | p. 594 |
Factors Affecting ¿ | p. 598 |
Consequences of Crystal Field Splitting | p. 600 |
Jahn-Teller Distortion | p. 603 |
Spectral Bands | p. 604 |
Molecular Orbitals in Complexes | p. 606 |
Interpretation of Spectra | p. 617 |
Splitting of Spectroscopic States | p. 617 |
Orgel Diagrams | p. 621 |
Racah Parameters and Quantitative Methods | p. 624 |
The Nephelauxetic Effect | p. 627 |
Tanabe-Sugano Diagrams | p. 629 |
The Lever Method | p. 633 |
Jørgensen's Method | p. 636 |
Charge Transfer Absorption | p. 637 |
Solvatochromism | p. 639 |
Composition and Stability of Complexes | p. 643 |
Composition of Complexes in Solution | p. 643 |
Job's Method of Continuous Variations | p. 645 |
Equilibria Involving Complexes | p. 647 |
Distribution Diagrams | p. 652 |
Factors Affecting the Stability of Complexes | p. 655 |
Synthesis and Reactions of Coordination Compounds | p. 665 |
Synthesis of Coordination Compounds | p. 665 |
Substitution Reactions in Octahedral Complexes | p. 671 |
Ligand Field Effects | p. 678 |
Acid-Catalyzed Reactions of Complexes | p. 681 |
Base-Catalyzed Reactions of Complexes | p. 682 |
The Compensation Effect | p. 684 |
Linkage Isomerization | p. 685 |
Substitution in Square Planar Complexes | p. 687 |
The Trans Effect | p. 690 |
Electron Transfer Reactions | p. 694 |
Reactions in Solid Coordination Compounds | p. 697 |
Complexes Containing Metal-Carbon and Metal-Metal Bonds | p. 707 |
Binary Metal Carbonyls | p. 707 |
Structures of Metal Carbonyls | p. 711 |
Bonding of Carbon Monoxide to Metals | p. 712 |
Preparation of Metal Carbonyls | p. 715 |
Reactions of Metal Carbonyls | p. 716 |
Structure and Bonding in Metal-Alkene Complexes | p. 721 |
Preparation of Metal-Alkene Complexes | p. 727 |
Chemistry of Cyclopentadienyl and Related Complexes | p. 728 |
Bonding in Ferrocene | p. 732 |
Reactions of Ferrocene and other Metallocenes | p. 735 |
Complexes of Benzene and Related Aromatics | p. 738 |
Compounds Containing Metal-Metal Bonds | p. 741 |
Coordination Compounds in Catalysis | p. 747 |
Elementary Steps in Catalytic Processes | p. 748 |
Homogeneous Catalysis | p. 761 |
Bioinorganic Chemistry | p. 773 |
What Metals Do in Some Living Systems | p. 773 |
Cytotoxicity of Some Metal Compounds | p. 784 |
Antimalarial Metallodrugs | p. 792 |
Ionization Energies | p. 797 |
Character Tables for Selected Point Groups | p. 801 |
Index | p. 807 |
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