Inorganic Chemistry

by
Edition: 2nd
Format: Hardcover
Pub. Date: 2012-10-30
Publisher(s): Academic Pr
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Summary

This concise textbook meets several objectives. First, the topics included were selected in order to provide essential information in the major areas of inorganic chemistry (molecular structure, acid-base chemistry, coordination chemistry, ligand field theory, solid state chemistry, etc.). These topics form the basis for competency in inorganic chemistry at a level commensurate with the one semester course taught at most colleges and universities. The second objective has been to stress fundamental principles in the discussion of several topics. For example, the hard-soft interaction principle is employed in discussion of acid-base chemistry, stability of complexes, solubility, and predicting reaction products. Third, the presentation of topics is made with an effort to be clear and concise so that the book is portable and user friendly. This book presents in convenient form a readable account of the essentials of inorganic chemistry that can serve as both as a textbook for a one semester course upper level course and as a guide for self study. Figures, tables, and end-of-chapter problems round out this pedagogically rich, thematically balanced text for advanced undergraduate and graduate level students. . Concise coverage maximizes student understanding and minimizes the inclusion of details students are unlikely to use. . Discussion of elements begins with survey chapters focused on the main groups, while later chapters cover the elements in greater detail. . Each chapter opens with narrative introductions and includes figures, tables, and end-of-chapter problem sets.

Table of Contents

Preface to the Second Editionp. xi
Preface to the First Editionp. xii
Structure of Atoms and Moleculesp. 1
Light, Electrons, and Nucleip. 3
Some Early Experiments in Atomic Physicsp. 3
The Nature of Lightp. 7
The Bohr Modelp. 11
Particle-Wave Dualityp. 14
Electronic Properties of Atomsp. 16
Nuclear Binding Energyp. 21
Nuclear Stabilityp. 23
Types of Nuclear Decayp. 25
Predicting Decay Modesp. 28
Basic Quantum Mechanics and Atomic Structurep. 33
The Postulatesp. 33
The Hydrogen Atomp. 40
The Helium Atomp. 45
Slater Wave Functionsp. 47
Electron Configurationsp. 49
Spectroscopic Statesp. 54
Covalent Bonding in Diatomic Moleculesp. 61
The Basic Ideas of Molecular Orbital Methodsp. 61
The H2+ and H2 Moleculesp. 69
Diatomic Molecules of Second-Row Elementsp. 71
Photoelectron Spectroscopyp. 77
Heteronuclear Diatomic Moleculesp. 79
Electronegativityp. 82
Spectroscopic States for Moleculesp. 85
A Survey of Inorganic Structures and Bondingp. 89
Structures of Molecules Having Single Bondsp. 89
Resonance and Formal Chargep. 99
Complex Structures: A Preview of Coming Attractionsp. 111
Electron-Deficient Moleculesp. 119
Structures Having Unsaturated Ringsp. 121
Bond Energiesp. 123
Symmetry and Molecular Orbitalsp. 129
Symmetry Elementsp. 129
Orbital Symmetryp. 137
A Brief Look at Group Theoryp. 139
Construction of Molecular Orbitalsp. 144
Orbitals and Anglesp. 150
Simple Calculations Using the Hückel Methodp. 152
Condensed Phasesp. 167
Dipole Moments and Intermolecular Interactionsp. 169
Dipole Momentsp. 169
Dipole-Dipole Forcesp. 174
Dipole-Induced Dipole Forcesp. 176
London (Dispersion) Forcesp. 177
The van der Waals Equationp. 181
Hydrogen Bondingp. 183
Cohesion Energy and Solubility Parametersp. 192
Solvatochromismp. 196
Ionic Bonding and Structures of Solidsp. 201
Energetics of Crystal Formationp. 201
Madelung Constantsp. 205
The Kapustinskii Equationp. 209
Ionic Sizes and Crystal Environmentsp. 210
Crystal Structuresp. 213
Solubility of Ionic Compoundsp. 219
Proton and Electron Affinitiesp. 224
Structures of Metalsp. 227
Defects in Crystalsp. 230
Phase Transitions in Solidsp. 233
Heat Capacityp. 234
Hardness of Solidsp. 237
Dynamic Processes in Inorganic Solidsp. 243
Characteristics of Solid-State Reactionsp. 243
Kinetic Models for Reactions in Solidsp. 245
Thermal Methods of Analysisp. 253
Effects of Pressurep. 254
Reactions in Some Solid Inorganic Compoundsp. 256
Phase Transitionsp. 258
Reactions at Interfacesp. 262
Diffusion in Solidsp. 263
Sinteringp. 265
Drift and Conductivityp. 267
Acids, Bases, and Solventsp. 271
Acid-Base Chemistryp. 273
Arrhenius Theoryp. 273
Brønsted-Lowry Theoryp. 276
Factors Affecting the Strength of Acids and Basesp. 279
Acid-Base Character of Oxidesp. 284
Proton Affinitiesp. 286
Lewis Theoryp. 288
Catalytic Behavior of Acids and Basesp. 292
The Hard-Soft Interaction Principle (HSIP)p. 296
Electronic Polarizabilitiesp. 305
The Drago Four-Parameter Equationp. 306
Chemistry in Nonaqueous Solventsp. 313
Some Common Nonaqueous Solventsp. 313
The Solvent Conceptp. 314
Amphoteric Behaviorp. 316
The Coordination Modelp. 317
Chemistry in Liquid Ammoniap. 318
Liquid Hydrogen Fluoridep. 324
Liquid Sulfur Dioxidep. 326
Superacidsp. 330
Chemistry of the Elementsp. 335
Chemistry of Metallic Elementsp. 337
The Metallic Elementsp. 337
Band Theoryp. 338
Groups IA and IIA Metalsp. 341
Zintl Phasesp. 349
Aluminum and Berylliump. 351
The First-Row Transition Metalsp. 353
Second- and Third-Row Transition Metalsp. 355
Alloysp. 357
Chemistry of Transition Metalsp. 360
The Lanthanidesp. 367
Organometallic Compounds of the Main Group Elementsp. 375
Preparation of Organometallic Compoundsp. 376
Organometallic Compounds of Group IA Metalsp. 378
Organometallic Compounds of Group IIA Metalsp. 380
Organometallic Compounds of Group IIIA Metalsp. 383
Organometallic Compounds of Group IVA Metalsp. 387
Organometallic Compounds of Group VA Elementsp. 388
Organometallic Compounds of Zn, Cd, and Hgp. 389
Chemistry of Nonmetallic Elements I. Hydrogen, Boron, Oxygen, and Carbonp. 393
Hydrogenp. 393
Boronp. 400
Oxygenp. 411
Carbonp. 420
Chemistry of Nonmetallic Elements II Groups IVA and VAp. 439
The Group IVA Elementsp. 439
Nitrogenp. 456
Phosphorus, Arsenic, Antimony, and Bismuthp. 471
Chemistry of Nonmetallic Elements EL Groups VIA-VTIIAp. 499
Sulfur, Selenium, and Telluriump. 499
The Halogensp. 520
The Noble Gasesp. 538
Chemistry of Coordination Compoundsp. 551
Introduction to Coordination Chemistryp. 553
Structures of Coordination Compoundsp. 553
Metal-Ligand Bondsp. 557
Naming Coordination Compoundsp. 559
Isomerismp. 561
A Simple Valence Bond Description of Coordinate Bondsp. 568
Magnetismp. 572
A Survey of Complexes of First-Row Metalsp. 574
Complexes of Second- and Third-Row Metalsp. 576
The 18-Electron Rulep. 576
Back Donationp. 580
Complexes of Dinitrogen, Dioxygen, and Dihydrogenp. 585
Ligand Fields and Molecular Orbitalsp. 591
Splitting of d Orbital Energies in Octahedral Fieldsp. 591
Splitting of d Orbital Energies in Fields of Other Symmetryp. 594
Factors Affecting ¿p. 598
Consequences of Crystal Field Splittingp. 600
Jahn-Teller Distortionp. 603
Spectral Bandsp. 604
Molecular Orbitals in Complexesp. 606
Interpretation of Spectrap. 617
Splitting of Spectroscopic Statesp. 617
Orgel Diagramsp. 621
Racah Parameters and Quantitative Methodsp. 624
The Nephelauxetic Effectp. 627
Tanabe-Sugano Diagramsp. 629
The Lever Methodp. 633
Jørgensen's Methodp. 636
Charge Transfer Absorptionp. 637
Solvatochromismp. 639
Composition and Stability of Complexesp. 643
Composition of Complexes in Solutionp. 643
Job's Method of Continuous Variationsp. 645
Equilibria Involving Complexesp. 647
Distribution Diagramsp. 652
Factors Affecting the Stability of Complexesp. 655
Synthesis and Reactions of Coordination Compoundsp. 665
Synthesis of Coordination Compoundsp. 665
Substitution Reactions in Octahedral Complexesp. 671
Ligand Field Effectsp. 678
Acid-Catalyzed Reactions of Complexesp. 681
Base-Catalyzed Reactions of Complexesp. 682
The Compensation Effectp. 684
Linkage Isomerizationp. 685
Substitution in Square Planar Complexesp. 687
The Trans Effectp. 690
Electron Transfer Reactionsp. 694
Reactions in Solid Coordination Compoundsp. 697
Complexes Containing Metal-Carbon and Metal-Metal Bondsp. 707
Binary Metal Carbonylsp. 707
Structures of Metal Carbonylsp. 711
Bonding of Carbon Monoxide to Metalsp. 712
Preparation of Metal Carbonylsp. 715
Reactions of Metal Carbonylsp. 716
Structure and Bonding in Metal-Alkene Complexesp. 721
Preparation of Metal-Alkene Complexesp. 727
Chemistry of Cyclopentadienyl and Related Complexesp. 728
Bonding in Ferrocenep. 732
Reactions of Ferrocene and other Metallocenesp. 735
Complexes of Benzene and Related Aromaticsp. 738
Compounds Containing Metal-Metal Bondsp. 741
Coordination Compounds in Catalysisp. 747
Elementary Steps in Catalytic Processesp. 748
Homogeneous Catalysisp. 761
Bioinorganic Chemistryp. 773
What Metals Do in Some Living Systemsp. 773
Cytotoxicity of Some Metal Compoundsp. 784
Antimalarial Metallodrugsp. 792
Ionization Energiesp. 797
Character Tables for Selected Point Groupsp. 801
Indexp. 807
Table of Contents provided by Ingram. All Rights Reserved.

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