Graphite Intercalation Compounds and Applications

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Format: Hardcover
Pub. Date: 2003-03-27
Publisher(s): Oxford University Press
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Summary

Graphite intercalation compounds are a new class of electronic materials that are classified as graphite-based host guest systems. They have specific structural features based on the alternating stacking of graphite and guest intercalate sheets. The electronic structures show two-dimensional metallic properties with a large variety of features including superconductivity. They are also interesting from the point of two-dimensional magnetic systems. This book presents the synthesis, crystal structures, phase transitions, lattice dynamics, electronic structures, electron transport properties, magnetic properties, surface phenomena, and applications of graphite intercalation compounds. The applications covered include batteries, highly conductive graphite fibers, exfoliated graphite and intercalated fullerenes and nanotubes.

Table of Contents

Introduction
3(6)
References
7(2)
Synthesis and Intercalation Chemistry
9(47)
Donor Intercalation Compounds
9(7)
Ternary Intercalation Compounds
16(15)
Acceptor Intercalation Compounds
31(13)
Bi-intercalation Compounds
44(12)
References
50(6)
Structures and Phase Transitions
56(62)
Overview and Definition
56(6)
Liquid State in Stage-2 Alkali Metal GICs
62(3)
Phase Transition in Stage-2 Alkali Metal GICs
65(8)
In-Plane Structure Model in High-Stage Alkali Metal GICs
73(7)
Liquid--Solid Transition in K GIC
80(4)
Two-Dimensional Melting in Stage-1 Rb GIC
84(4)
Staging Structure
88(6)
Hendricks--Teller Stage Disorder
94(5)
Fractional Stage
99(4)
Stripe Domain Phase in Br2 GIC
103(4)
Phase Transition in SbCl5 GIC
107(3)
Ordering Kinetics
110(8)
References
115(3)
Lattice Dynamics
118(25)
Phonon Dispersion in Alkali Metal GICs (Theory)
118(4)
Phonon Dispersion in Alkali Metal GICs (Experiment)
122(5)
Raman Scattering
127(8)
Donor--Acceptor Graphite Bi-intercalation Compound
135(1)
Intercalate Diffusion
136(7)
References
141(2)
Electronic Structures
143(47)
Band Structure of Graphite, and Tight Binding Model for GICs
143(12)
Acceptor GICs
155(9)
Alkali Metal GICs
164(14)
GICs with Novel Intercalates
178(12)
References
186(4)
Electron Transport Properties
190(46)
In-Plane Electron Transport Process
190(8)
c-Axis Conduction Process
198(8)
Weak Localization
206(7)
Transport Properties of Magnetic GICs
213(6)
Superconductivity
219(17)
References
232(4)
Magnetic Properties
236(58)
Overview
236(2)
Stage-2 CoCl2 GIC
238(16)
Stage-2 MnCl2 GIC
254(12)
Stage-2 CuCl2 GIC
266(7)
Stage-2 FeCl3 GIC
273(10)
Stage-1 Eu GIC (EuC6)
283(6)
Magnetic Ternary (Quaternary) GICs
289(5)
References
290(4)
Surface Properties and Gas Adsorption
294(42)
Gas Physisorption in Alkali Metal GICs
294(23)
Surface Properties and Monolayer
317(19)
References
332(4)
GICs and Batteries
336(52)
Application of Intercalated Graphite in Primary Battery System
336(18)
Secondary Battery Applications as Li Ion Battery
354(34)
References
384(4)
Highly Conductive Graphite Fibers
388(15)
Introduction
388(1)
Structure and Staging
389(1)
Intercalate-Induced Enhancement of Conductivity
390(4)
Stability of Intercalated Graphite Fibers
394(1)
Fluorine-Intercalated Graphite Fibers with Ionic Bonding
395(3)
Conclusions
398(5)
References
400(3)
Exfoliated Graphite Formed by Intercalation
403(11)
Introduction
403(1)
Structural Variation after the Exfoliation Process
404(2)
Exfoliation Process
406(1)
Exfoliated Graphite Fibers
407(1)
Applications
408(4)
Conclusions
412(2)
References
412(2)
Intercalated Fullerenes and Carbon Nanotubes
414(19)
Introduction
414(2)
Preparation and Structure of Pristine and Intercalated Fullerenes
416(6)
Preparation and Structure of Intercalated Carbon Nanotubes and Potential Applications
422(6)
Conclusions
428(5)
References
429(4)
Index 433

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